Photodetectors of IR radiation oh the base of CdS1-xSex films, deposited from solution

A. Sh. Abdinov, M. A. Jafarov, N. M. Mechtiyev, H. M. Mamedov, E. F. Nasirov
Baku State University, Azerbaijan

In this work the results on the investigation of the photosensitivity near the IR region, of CdS1-xSex (0 <= x <= 0,4) films 8-9 mm thick prepared on glass-ceramic substrates by precipitation from aqueous solutions are presented. The temperature dependence of dark and light conductivity, spectrum and optical quenching of primary and impurity photoconductivity are in vestigated. The obtained results show that when controlling ionic composition and heat-treatment (HT) conditions, one can purposely control the properties of CdS1-xSex (0 <= x <= 0,4) films, achieve the appropriate degree of compensation of different recombination levels and traps attributed to intrinsic defects or impurities, which result in high level of photoelectrical parameters near the IR region. Just after deposition the photoconductivity spectrum maximum of CdS1-xSex (0 <= x <= 0,4) films is observed at l1 = 0,495-0,545 mm versus the film composition. Subsequent to HT, the photoconductivity spectrum considerably widens and appears the impurity maximums at l2 = 0,58-0,69 mm and l3 = 0,95-1,05 mm. At l1 = 0,88-1,56 mm wavelength region, the primary photocurrent optical quenching (POQ) of the films takes place. The POQ spectrum in photosensitive CdS1-xSex films consists band with the maximum at lmax = = 1,28-1,38 mm, versus the film composition and HT conditions. At optimum conditions, the degree of quenching attains to 12 %. The quenching of the primary photoconductivity by infrared light, leads to the occupation of the r-centers by holes.

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